PROGRAM TITLE: Global Tropospheric Chemistry Program (GTCP) ACTIVITY STREAM: Process, Observe, Model, Data SCIENCE ELEMENT:Biogeochemical Dynamics NATIONAL SCIENCE FOUNDATION SCIENTIFIC MERIT: The Global Tropospheric Chemistry Program is a focused atmospheric chemistry program designed to provide a better understanding of how substances of natural or anthropogenic origin enter the atmosphere, are physically and chemically transformed, and ultimately removed. The overall objective of this program is to measure, understand, and thereby predict changes in the chemistry of the global atmosphere with particular emphasis on changes affecting the radiative properties and oxidizing capacity of the atmosphere and the atmospheric component of biogeochemical cycles. This objective is to be accomplished through field and laboratory investigations as well as theory aided by appropriate statistical and mathematical modeling. Augmentation of the base is required to permit NSF supported scientists at the Universities and the National Center for Atmospheric Research to participate in major international regional field experiments in FY 1995 through FY 1999 and to identify, analyze, and develop mathematical and statistical models of atmospheric chemistry that can be used for process understanding and climate prediction purposes. Laboratory investigations of the mechanisms and rates of key chemical reactions will also be supported under this program. A portion of the program's funds will be used to help offset the costs of development, procurement and evaluation of advanced instrumentation required for future observational projects. Major GTCP activities, including aircraft and land-based field observations to investigate the atmospheric cycles of carbon, nitrogen, sulfur, and oxidant species, and the development of tropospheric chemistry models, have been and are currently being planned and scheduled for the period 1995-1999. GTCP participation in multi-agency and international field projects scheduled for 1995 and beyond include studies of surface exchange processes in the tropics; photochemistry experiments in the atmosphere over the Atlantic and Pacific oceans; and studies of the role of atmospheric sulfur compounds on the distribution of aerosols and cloud physical properties. STAKEHOLDERS: The NSF GTCP is part of a multi-agency and international tropospheric chemistry research effort. NASA, NOAA and NSF have assumed the initial responsibility for nurturing a U.S. atmospheric chemistry research program focused on Global Change issues and ensuring a long-term support base. DOE and EPA are also planning to make significant contributions to this global research effort. An international research effort, the International Global Atmospheric Chemistry (IGAC) Programme, that is responsive to the needs of the IGBP has been developed by the ICSU International Association of Meteorology and Atmospheric Physics' Commission on Atmospheric Chemistry and Global Pollution (CACGP). IGAC was adopted as the first core project of the IGBP in 1989 and the focused IGAC projects contributing to the research programme were published in 1990 in IGBP Report 12 and IGBP Report 13. Project implementation plans for several IGAC campaigns were published in 1993. The IGAC activities are focused on international atmospheric chemistry experiments that will provide knowledge of the sources and sinks of greenhouse gases and aerosols and the processes that control their distributions and lifetimes in the atmosphere. The Global Tropospheric Chemistry Program is the NSF's contribution to the IGAC Programme. POLICY RELEVANCE: In the short-term, field, laboratory, and theoretical tests will allow identification of greenhouse gas sources, sinks and lifetimes, the role of anthropogenic sulfate aerosols in offsetting trace-gas greenhouse warming, and an improved understanding of the factors which control the oxidizing capacity of the atmosphere. This new knowledge will support U.S. environmental commitments, for example, in climate change, global warming, and stratospheric ozone. Over the longer term, incorporation of these and other chemical processes in global chemistry and climate models will allow improved predictions and assessments of future changes in atmospheric composition and the resulting impact such changes may have on climate forcing. PROGRAM CONTACT:Jarvis Moyers, Atmospheric Chemistry Program Director